The large lattice dynamics of lithium, driven by its low atomic mass, results in energetically similar structures and significant isotope effects under pressure, posing challenges to current theoretical models. Above 20 GPa and at low temperatures, lithium's electronic properties deviate from simple metallic behavior, with superconductivity emerging in a complex, pressure-dependent manner, alongside an unusual isotope effect. The structural phases of 7Li reported under these conditions are inconsistent across studies, and the structures of 6 Li remain unexamined. These gaps limit our understanding of the effects of pressure on lithium's electronic properties and the role of quantum lattice effects on its structural behavior under pressure. Here, we integrate experimental and theoretical approaches to investigate the low-temperature structural phase boundaries in lithium isotopes. We map the structural phase diagram of 7Li from 5 to 55 GPa and 15–75 K, identifying the sequence fcc→ℎ⁡𝑅⁢1→𝑐⁢𝐼⁢16. A pronounced isotope effect is observed, with 6Li shifting the fcc→ℎ⁡𝑅⁢1 phase boundary to lower pressures at 15 K. Density functional theory calculations further clarify how these structural changes affect superconducting properties, particularly emphasizing the role of the fcc→ℎ⁡𝑅⁢1 transition in lithium's superconductivity. Our findings offer insights into the unique behavior of lithium isotopes under pressure.

Last modified

• 03/03/2025

Creator

• Holle, William
• Deemyad, Shanti
• Saffarian-Deemyad, Iren

Subject

• Lithium--Isotopes

Identifier

• doi.org/10.7278/S5d-aq4d-1d3k

Keyword

• lithium isotopes

Date created

• 2019-10-10 to 2022-12-20

Source

• Library of Congress Subject Headings (LCSH)

License

• CCO – As the data author, you are choosing to place your data into the public domain.